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Formation of Diazonium Salts

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Select the incorrect option for the following statements. (a) bimolecular elimination of alkyl halides is a stereo specific reaction (b) inner SN2 reaction a single isomer is the only product (c) n-propyl alcohol dehydrates in strongly basic conditions by E1cB mechanism (d) 3-hydroxypropanal dehydrates in strongly basic conditions by E1cB mechanism

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Q. An incorrect statement with respect to

S_{N} 1

S_{N} 2

mechanism for alkyl halide is :

Q. Alkyl halides and alcohols easily undergo nucleophilic substitution either through

S_{N} 1

S_{N} 2

mechanism. The relative case of these two processes depends upon the nature of the substrate (alkyl group) as well as leaving group, nature of nucleophile and also upon the nature of the solvent.

S_{N} 1

mechanism involves the formation of carbocation as intermediate while

S_{N} 2

mechanism involves the formation of a transition pentavalent state.

S_{N} 1

is the main mechanism in

3^{0}

alkyl halides and alcohols, while

S_{N} 2

mechanism is the path adopted by most of the

1^{o}

2^{o}

alkyl halides may follow

S_{N} 1

S_{N} 2

.

What happens when

1^{o} R O H

H X

Q. Which of the following alkyl halide is most reactive towards substitution on reaction by

S_{N} 1

Q. Explain the mechanism of esterification. Write the reactions involved in dehydration of

1^{o}

2^{o}

3^{o}

Q. Tertiary alkyl halides are particularly not substituted by

S_{N} 2

mechanism, because of:

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Formation of Diazonium Salts

Standard XII Chemistry

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