The correct option is A 2-carbon compound - PEP
PEP (phosphoenol pyruvate) carboxylation gives the four-carbon organic acid oxaloacetate (OAA), which is rapidly converted into the organic acids malate or aspartate. These acids are then transported to the inner compartment where a decarboxylating enzyme breaks them down to CO2 and either pyruvate (in most species) or PEP. Hence, PEP is a three carbon compound. Hence, option a is incorrectly matched.
Phosphoglyceric acid, malic acid and ribulose 1,5-bisphosphate are three, four and five carbon compounds respectively.