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Question

Select the incorrect statement(s).

A
IE1 of Nitrogen atom is less than IE1 of Oxygen atom.
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B
Electron gain enthalpy of Oxygen is less negative than Selenium.
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C
Electronegativity on Pauling scale is 2.8 times the electronegativity on Mulliken scale.
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D
Cr6+ is smaller than Cr3+.
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Solution

The correct options are
A IE1 of Nitrogen atom is less than IE1 of Oxygen atom.

C Electronegativity on Pauling scale is 2.8 times the electronegativity on Mulliken scale.

(A,C)
(A) IE1of N is more than O due to stable half filled electronic configuration of valence shell in N.
(B) Electron gain enthalpy of O (-141 kJmol1) is less than Sulphur and Selenium due to its exceptionally small atomic size.
(C) Electronegativity on mulliken scale is 2.8 times larger than electronegativity on pauling scale.
(D) The ionic radius decreases as more electrons are ionized off/removed.

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