The correct options are
B As2O3
C Na2C2O4
A primary standard is a reagent that is extremely pure, stable, has no water of hydration and has a high molecular weight.
As2O3, Na2C2O4 act as primary standard reagents.
Ce(NO3)4, Na2CO3 are not primary standard reagents because they have less molecular weight and they can be hydrated.
Hence, options B and C are correct.