The correct option is A
Intrinsic Semiconductor
The conduction by pure substances such as silicon and germanium exhibiting electrical conductivity are called intrinsic semiconductors.
Atoms of Si and Ge, both have four electrons in their outer shell.
At very low temperatures, the valence band is filled and the conduction band is empty in Si and Ge.
Under these conditions, Si and Ge are both insulators, and cannot carry any electric current.
The conductivity of pure silicon and germanium is low at room temperature, so, to increase the conductivity the process doping comes.