Setting of plaster of paris is
Hydration to yield another hydrate
Setting of plaster of paris is exothermic process
CaSO4.12H2O H2O−−−→ CaSO4.2H2O Hardening−−−−−−−−→ CaSO4.2H2O
Orthorhombic Monoorthorhombic Gypsum
The setting is due to formation of another hydrate