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Electrophilic Substitution Reactions of Haloarenes

shouldnt tert...

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shouldnt tert butyl bromide undergo sn1 instead of e1

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S N^{1}

mechanism for the hydrolysis of tert-butyl bromide.

Q. a) Write equations for the steps in

S_{N} 1

mechanism of the conversion of tert. butyl bromide into tert. butyl alcohol.
b) Identify the products

A, B

C

in the following equation

C H_{3} O H R e d P - -- \to C l_{2} A N a I - ----- \to d r y a c e t o n e B C_{6} H_{5} I - -------- \to N a a n d d r y e t h e r C

Q. Arrange the following alkyl chlorides in order of decreasing reactivity in a

S_{N} 1

reaction.
(I) isopropyl bromide
(II) propyl bromide
(III) tert-butyl bromide
(IV) methyl bromide

Q. The alkyl halide that undergoes

S N_{1}

reaction more readily is

Q. a) Write the equations for the steps in

S_{N} 1

mechanism of the conversion of teri-Butyl bromide into tert-Butyl alcohol.
b) Explain Fitting reaction.
c) Name the reagent used in the dehydrohalogenation of haloalkanes.

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Electrophilic Substitution Reactions of Haloarenes

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