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Polar Covalent Compounds

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Question

Show the polarization of carbon-magnesium bond in the following structure.
$C H_{3} - C H_{2} - C H_{2} - C H_{2} - M g - X$

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Solution

$C H_{3} - C H_{2} - C H_{2} - δ - C H_{2} - δ + M g - X$

Carbon is more electronegative than magnesium therefore, Mg has partial positive charge and C has a partial negative charge because bonded pair of electrons are attracted more towards carbon.

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Q. The nature of C-X bond in

C H_{3} - C H_{2} - C H_{2} - X

Q. Write the IUPAC names of the following structural formulae.

a. CH₃-CH₂-CH₂-CH₃	b. CH₃-CHOH-CH₃
c. CH₃-CH₂-COOH	d. CH₃-CH₂-NH₂
e. CH₃-CHO	f. CH₃-CO-CH₂-CH₃

C H_{3} - C H_{2} - O | | C - C H_{2} - C H_{3}

C H_{3} - C H_{2} - C H_{2} - O | | C - C H_{3}

Write the structure of alkynes that give following ketones on hydration.

Q. Identify the type of the following reaction of carbon compounds.
a. CH₃ -CH₂ -CH₂-OH → CH₃ -CH₂ -COOH
b. CH₃ -CH₂ -CH₃ → 3CO₂ + 4H₂O
c. CH₃ -CH = CH -CH₃ + Br₂ → CH₃ -CHBr - CHBr -CH₃
d. CH₃ -CH₃ + Cl₂→ CH₃ -CH₂ -Cl + HCl
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f. CH₃-CH₂ -COOH + NaOH → CH₃ -CH₂ -COO - Na⁺ + H₂O
g. CH₃ -COOH + CH₃ -OH → CH₃ -COO- CH₃ + H₂O

Q. The correct order of C - H bond length in

C H_{3} - C H_{3}, C H_{2} = C H_{2}

C H \equiv C H

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