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Question

Si of high purity to be used in semiconductor can be prepared by following methods :

I. SiO2+2CSi+2CO

II. Si+2Cl2SiCl4

SiCl4+2MgSi+2MgCl2

Better method is :

A
I
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B
II
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C
both (A) and (B)
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D
None of these
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Solution

The correct option is A II
Si of high purity to be used in semiconductor can be prepared by the reaction of Si with chlorine to form SiCl4 followed by fractional distillation (to purify SiCl4) and reduction with hydrogen. Zone refining is used for the further purification.
Si+2Cl2SiCl4(l)2H2(g)−−−Si(s)+4HCl(g)Zonerefining−−−−−−−Ultrapuresilicon

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