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Question

Silver jewellary turns black on long exposure to air. This is due to the formation of:

A
Ag2O
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B
Ag3N
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C
Ag2O+Ag3N
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D
Ag2S
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Solution

The correct option is D Ag2S
Silver is stable in pure water and air but tarnishes when it is exposed to air or water containing hydrogen sulfide, the latter forming a black layer of silver sulfide which can be cleaned off with dilute HCl.
2Ag+H2SAg2Sblack.+H2

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