SnCl2.2H2O Δ→ ?–+HCl+H2O
Here, we have to think what happens when hydrated stannous chloride is heated.
On heating hydrated stannous chloride, SnCl2.2H2O, it undergoes hydrolysis, resulting in the formation of tin hydroxyl chloride, a white solid.
SnCl2.2H2O Δ→ Sn(OH)Cl+HCl+H2O
Hence, anhydrous stannous chloride cannot be obtained by heating hydrated stannous chloride.