Sodium carbonate can be manufactured by solvay's process but potassium carbonate cannot be prepared because:
KHCO3 is more soluble than NaHCO3
Sodium carbonate can be manufactured by solvay's process but potassium carbonate cannot be prepared because KHCO3 is more soluble than NaHCO3.Sodium bicarbonate when heated we get sodium carbonate.
NaHCO3 → Na2CO3 + H2O + CO2
But where as we cannot do the same in case of potassium bicarbonate as it is more soluble.