The correct option is D low value of first I.E and high value of second I.E
Na (Z=11;1s2,2s2p6,3s1) readily gives one electron because the resulting Na+ (1s22s2p6) has stable configuration. Thus, the first I.E of Na is less. However, removal of an electron from a stable (noble gas) configuration requires high energy and thus, its second I.E is very high.