Sodium salt of benzoic acid on heating with sodalime gives a hydrocarbon 'A' along with sodium carbonate. The compound 'A' on treatment with excess of chlorine in the presence of anhydrous AlCl3 will give
A
Hexachlorobenzene
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B
Hexachlorocyclohexane
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C
2,4,6−Trichlorophenol
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D
1,4−Dichlorobenzene
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Solution
The correct option is A Hexachlorobenzene Sodium salt of benzoic acid on heating with sodalime gives a hydrocarbon benzene along with sodium carbonate. Benzene on treatment with excess of chlorine in the presence of anhydrous AlCl3 will give hexachlorobenzene.