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Question

Solid AB has CsCl type structure. If the radius of A+ ion is 73.2 pm then the minimum radius of B (in pm) ion will be:

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Solution

In CsCl, the coordination number of both Cs+ and Cl is 8.
AB has similar type of structure with CsCl.
If rA+ is the radius of cation A+ and rB is the radius of anion B, then
rA+rB=0.73273.2rB=0.732
rB=100 pm

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