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Question

Solubility product constant (Ksp) of salts of types MX, MX2 and M3X at temperature 'T' are 4.0 × 108,3.2 ×1014 and 2.7×1015, respectively. Solubilities (mol dm3) fo the salts at temperature 'T' are in the order

A
MX>MX2>M3X
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B
M3X>MX2>MX
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C
MX2>M3X>MX
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D
MX>M3X>MX2
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Solution

The correct option is D MX>M3X>MX2
MX: Ksp=S2=4×108
S=2×104
MX2: Ksp=4S3=3.2×1014 S=2×105
M3X: Ksp=27S4=2.7×1015 S=104
Order of solubility is MX>M3X>MX2

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