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Question

Solution A,B,C and D are respectively 0.1M Glucose, 0.05M NaCl, 0.05M BaCl2 and 0.1M AlF3. which one of the following pairs is isotonic?

A
A&C
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B
B&C
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C
A&B
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D
A&D
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Solution

The correct option is D A&B
The solutions A (0.1 M glucose) and B (0.05 M NaCl) are isotonic.
They have the same osmotic pressure. The product of molar concentration and the number of ions obtained on dissociation of 1 molecule of solute is the same for both solutions. Glucose is non-electrolyte and does not dissociate. Hence the product will be, 0.1×0.1 = 0.1
One molecule of NaCl dissociates to give two ions,
Hence the product is 0.05×2 =0.1
C is the correct option.

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