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Question

Some amount of NH4Cl was boiled with 50 mL of 0.75 N NaOH solution till the reaction was complete. After the completion of the reaction, 10 mL of 0.75 N H2SO4 were required for the neutralisation of the remaining NaOH. Calculate the amount of NH4Cl taken.

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Solution

N1V1+N2V2V1+V2=N50×0.75+10×0.75×260=N
37.5+1560=N=52.560=0.875N
AmountofNH4ClmolarmassofNH4Cl=N×vol.0.875×0.06=0.00525
AmountofNH4Cl=53.4×0.00525=0.27025g.

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