The correct option is D Water
Chemiosmotic hypothesis explains how ATP is synthesized in the chloroplast. ATP synthesis is linked to the development of a proton gradient across the membrane of the thylakoid of chloroplast and proton accumulation is towards the inside of the membrane i.e., in the lumen. Source of protons within the chloroplasts is water. The splitting of water molecule takes place on the inner side of the membrane and so the protons (hydrogen ions) are produced, they accumulate within the lumen of the thylakoids. Thus, the correct answer is option A.