The correct option is D In angiosperms and gymnosperms, pollen contains sporopollenin, while in bryophytes and pteridophytes, sporopollenin is absent.
Sporopollenin is a highly resistant and inert chemical that constitutes the outer wall of pollen grains of angiosperms. It protects the male gametes from high temperature, effects of acids and alkalis.
Sporopollenin has been shown to be present in some bryophytes, pteridophytes and gymnosperms as well.