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Question

Spin only magnetic moment of an octahedral complex of Fe2+ in the presence of a strong field ligand in BM is

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A
0
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B
2.82
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C
4.89
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D
3.46
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Solution

The correct option is A 0
The electronic configuration of Fe2+ is 3d64s0. In presence of strong field ligand (L) resulting in the formation of inner orbital octahedral complex the electronic configuration of Fe2+ would be
[FeL6]4:t62e0g
No unpaired electron, so,
Magnetic moment, μ=0


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