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Question

Spin only magnetic moments of a d8 ion in octahedral, square planar, and tetrahedral complexes, respectively, are :

A
2.8 B.M., 0, and 2.8 B.M.
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B
2.8, 2.8, and 2.8 B.M.
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C
0, 0, and 0 B.M.
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D
None of these
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Solution

The correct option is B 2.8 B.M., 0, and 2.8 B.M.
As we know,
Magnetic moment = n(n+2)
In octahedral complex it will have 2 unpaired electron so μ=2.8BM
square planar complex, it will have zero unpaired electron so
μ=0
and tetrahedral complex
it will have 2 unpaired electron so μ=2.8BM

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