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Question

Standard electrode potential for Sn4+/Sn2+ couple is +0.15V and that for the Cr3+/Cr couple is 0.74V. these two couples in their standard state are connected to make a cell. the potential will be

A
+1.19 V
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B
0.89 V
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C
+1.83 V
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D
+0.18 V
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Solution

The correct option is B 0.89 V
Sn4++2eSn2+;Eo=+0.15V
Cr3++3eCr;Eo=0.74V
Ecell=Ecathode(RP)Eanode(RP)
Ecell=0.15(0.74)=+0.89 V

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