Standard enthalpy and standard entropy change for the oxidation of NH3 at 298K are −382.64kJmol−1 and −145.6kJmol−1 respectively. Standard Gibbs energy change for the same reaction at 298K is:
A
+339.3kJmol−1
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B
−439.3kJmol−1
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C
−339.3kJmol−1
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D
−393.3kJmol−1
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Solution
The correct option is D−393.3kJmol−1 Standard enthalpy and standard entropy change for the oxidation of NH3 at 298K are −382.64kJmol−1 and −145.6Jmol−1K−1 respectively.
Standard Gibbs energy change for the same reaction at 298K is −393.3kJmol−1 ΔG0=ΔH0−TΔS0 ΔG0=−382.64kJmol−1−(298K×(−145.6Jmol−1K−1)×10−3kJ/J) ΔG0=−393.3kJmol−1