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Question

Standard enthalpy of combustion of CH4 is 890 kJ mol1 and standard enthalpy of vaporisation of water is 40.5 kJ mol1. Calculate the enthalpy change for the reaction :
CH4(g)+2O2(g)CO2(g)+2H2O(g)


A

890 kJ mol1

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B

809 kJ mol1

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C

809 kJ mol1

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D

971 kJ mol1

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Solution

The correct option is B

809 kJ mol1


CH4(g)+2O2(g)2CO2(g)+2H2O.ΔH=890 kJ ...(i)
2H2O()2H2O(g),ΔH=2×40.5=81 kJ ...(ii)
(i)+(ii),CH4(g)+2O2(g)2CO2(g)+2H2O(g)ΔH=890+81=809 kJ


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