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Question

Standard reduction potentials of the half reactions are given below
F2(g)+2e2F(aq); E0=+2.85 V
Cl2(g)+2e2Cl(aq); E0=+1.36 V
Br2(l)+2e2Br(aq); E0=+1.06 V
I2(s)+2e2I(aq); E0=+0.53 V

The strongest oxidising and reducing agents respectively are:

<!--td {border: 1px solid #ccc;}br {mso-data-placement:same-cell;}--> AIPMT 2012 Mains

A
F2 and I
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B
Cl2 and Br
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C
Br2 and Cl
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D
Cl2 and I2
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Solution

The correct option is A F2 and I
Because of high standard reduction potential of F2, it readily reduces to F. So it oxidises other elements strongly. So, it is the strongest oxidising agent.
I2 has the lowest standard reduction potential here. I oxidises itself strongly and reduces others. So, it is a strong reducing agent.
Hence, option (a) is correct.

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