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Question

Standing waves of frequency 5.0 kHz are produced in a tube filled with oxygen at 300 K. The separation between the consecutive nodes is 3.3 cm. Calculate the specific heat capacities Cp and Cv of the gas.

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Solution

Frequency of standing waves, f = 5 × 103 Hz
Temperature of oxygen, T = 300 K
From Kundt's tube theory, we know that
l2 = node separation = 3.3 cm
∴ l = 6.6 × 10−2 m
Also,
v = fl = 5 × 103 × 6.6 × 10−2
= (66 × 5) = 330 m/s
v=γRTM v2=γRTM γ=330×330×328.3×300×100=1.3995Specific heat at constant volume, Cv=Rγ-1=8.30.3995

= 20.7 J mol-K

Specific heat at constant pressure, Cp = Cv + R
Cp = 20.7 + 8.3
Cp = 29.0 J/mol-K

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