Starch is used as a best indicator in iodometric titration because :
Iodometry, also known as iodometric titration, is a method of volumetric chemical analysis, a redox titration where the appearance or disappearance of elementary iodine indicates the end point.
The indicator that is usually chosen for titrations involving iodine is starch. Starch forms a dark blue complex with iodine. The end point in iodimetry corresponds to a sudden color change to blue.
Also It is can be freshly prepared and is non toxic in nature. Hence, starch is used as an indicator in iodometric titration.