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Question

State proper steps for writing chemical formulae from the knowledge of valency. Give an example in support of your answer.


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Solution

Definition of chemical formulae

A chemical formula identifies each constituent element by its chemical symbol and indicates the proportionate number of atoms of each element. In empirical formulae, these proportions begin with a key element and then assign numbers of atoms of the other elements in the compound, by ratios to the key element.

Definition of valency

valency of an element is the measure of its combining capacity with other atoms when it forms chemical compounds or molecules.

Steps for writing chemical formula

To write the chemical formula for a compound it is best to use the S.V.S.D.F system.

  • S - write down the symbols of both the elements involved.
  • V - beneath each symbol, write its valency
  • S - swap the valencies over.
  • D - if the valencies can be simplified, divide them both by the smaller of the two numbers

For example,

  • Potassium Chloride:

Name of the elements
Symbol

Valency

PotassiumK1+
ChlorineCl1-

Positive ions are written first

On interchanging the valencies

Formula = KCl

  • Calcium hydroxide

Name of the elementsSymbolValency
CalciumCa2+
HydroxideOH1-

Positive ions are written first

On interchanging the valencies

Formula = Ca(OH)2


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