The correct option is A True
The given statement is true.
For hydrogen atom, the energies of the sub-shells 4s,4p,4d and 4f are in the order: 4f>4d>4p>4s. This is the same order in which the value of the azimuthal quantum number, l, increases.
With an increase in the value of the azimuthal quantum number, l, the energy of the subshell increases.