In the purification of bauxite ore as a preliminary step in the production of Al, [Al](OH)4]− can be converted to Al(OH)3 by passing CO2 through it.
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Solution
Aqueous solution of CO2 is acidic. Hence, CO2 when passed into [Al(OH)4]− solution makes it acidic hence, Al(OH)3 is precipitated. CO2+2H2O→H3O++HCO−3[Al(OH)4]−+H3O+→Al(OH)3↓+2H2O