Out of the following acid base-reactions, reaction (b) and(c) are possible. a. PH3+⊕NH4⟶⊕PH4+NH3 b. NH3+P⊕H4⟶N⊕H4+PH3 c. (CH3)3P+⊕NH4⟶(CH3)3⊕PH+NH3 d. (CH3)3N+PH⊕4⟶(CH3)3⊕NH+PH3
A
True
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B
False
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Solution
The correct option is A True a. PH3+⊕NH4⟶⊕PH4+NH3 b. NH3+P⊕H4⟶N⊕H4+PH3 c. (CH3)3P+⊕NH4⟶(CH3)3⊕PH+NH3 d. (CH3)3N+PH⊕4⟶(CH3)3⊕NH+PH3 Out of the above acid base-reactions, reaction (b) and (c) are possible due to following reasons. Ammonia is more basic than phosphine Ammonia is less basic than (CH3)3P