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Question

State True or False.
Out of the following acid base-reactions, reaction (b) and(c) are possible.
a. PH3+NH4PH4+NH3
b. NH3+PH4NH4+PH3
c. (CH3)3P+NH4(CH3)3PH+NH3
d. (CH3)3N+PH4(CH3)3NH+PH3

A
True
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B
False
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Solution

The correct option is A True
a. PH3+NH4PH4+NH3
b. NH3+PH4NH4+PH3
c. (CH3)3P+NH4(CH3)3PH+NH3
d. (CH3)3N+PH4(CH3)3NH+PH3
Out of the above acid base-reactions, reaction (b) and (c) are possible due to following reasons.
Ammonia is more basic than phosphine
Ammonia is less basic than (CH3)3P

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