ions.
For the two ions of the same size and charge, one with a pseudo noble gas configuration (i.e 18 electrons outermost shell) will be more polarizing than a cation with noble gas configuration (i.e., 8 electrons outermost shell).
The electronic configuration of Zn2+ ion is [Ar]3d104s0. It has pseudo noble gas configuration.
The electronic configuration of Ca2+ ion is [Ar]. It has noble gas configuration.