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Question

State whether the given statement is true or false :
β-Keto acid shown above does not undergo decarboxylation reaction.
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Solution

Keto acid shown above does not undergo decarboxylation reaction.
This is because, the carbanion formed after a loss of CO2 is not stabilized by resonance with the adjacent carbonyl group, due to non-planarity of p-orbital of bridge head carbon and carbonyl carbon.

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