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Question

STATEMENT-1 : Acetanilide is more reactive than aniline towards electrophilic substitution reactions.

STATEMENT-2 : The activating effect of NHCOCH3 is less than that of amino group.


A
STATEMENT-1 is True, STATEMENT-2 is True; STATEMENT-2 is a correct explanation for STATEMENT-1
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B
STATEMENT-1 is True, STATEMENT-2 is True; STATEMENT-2 is NOT a correct explanation for STATEMENT-1
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C
STATEMENT-1 is True, STATEMENT-2 is False
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D
STATEMENT-1 is False, STATEMENT-2 is True
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Solution

The correct option is D STATEMENT-1 is False, STATEMENT-2 is True
NHCOCH3 group decreases the electron density of benzene ring whereas NH2 group increases the electron density of benzene ring. Hence, the activating effect of NHCOCH3 is less than that of amino group. Hence, acetanilide is more reactive than aniline towards electrophilic substitution reactions.

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