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Question

Statement 1: An endothermic reaction can be spontaneous
Statement 2: Both the enthalpy and the entropy changes affect the Gibbs free-energy change of the reaction.

A

Both Statement 1 and Statement 2 are correct and Statement 2 is the correct explanation of Statement 1.


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B

Both Statement 1 and Statement 2 are correct and Statement 2 is not the correct explanation of Statement 1.


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C

Statement 1 is correct but Statement 2 is not correct.

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D

Statement 1 is not correct but Statement 2 is correct.

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E

Both the Statement 1 and Statement 2 are not correct.

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Solution

The correct option is C

Both Statement 1 and Statement 2 are correct and Statement 2 is not the correct explanation of Statement 1.



For a spontaneous reaction :

G()ve

i.e. HTS()ve

G can be negative if :

a) H()ve
S(+)ve

b)H(+)ve
T(+)ve
TS>H

Hence, statement 1 is correct.

eg- ice is melting at room temperature

Also, statement 2 is correct as change in gibbs energy(G) depends on enthalpy change (H) and entropy change(S)

Statement 2 doesn't explain statement 1

eg- ice cube melts at room temperature because of increase of entropy overcomes the change to a higher energy state.
Hence, Statement 2 is not the correct explanation of statement 1

The option is B.

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