Statement 1: Increasing temperature increases the density of point defects. Statement 2: The process of formation of point defects in solids is endothermic and has ΔS>0.
A
Statement-1 is true, Statement-2 is true and Statement-2 is the correct explanation for Statement-1
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B
Statement-1 is true, Statement-2 is true and Statement-2 is not the correct explanation for Statement-1
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C
Statement-1 is true, Statement-2 is false
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D
Statement-1 is false, Statement-2 is true
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Solution
The correct option is A Statement-1 is true, Statement-2 is true and Statement-2 is the correct explanation for Statement-1 The process of formation of point defects in solids is endothermic.
Hence, ΔH>0 and also, ΔS>0. When temperature is increased, ΔG=ΔH−TΔS<0. The process of formation of defects become spontaneous. Hence, more and more defects are created per unit volume. Thus, increasing temperature increases the density of point defects.