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Question

Statement 1: The Friedel-Craft alkylation of nitro-benzene gives metals alkylated nitro benzene.
Statement 2: Nitro group is metal directing aromatic electrophilic substitution as it decreases electron density at o & p position.
Comment on the above statement.

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Solution

Statement 1 is false as nitrobenzene deactivates the range and deactivated range does not support alkylation.

Statement 2 is true as -M effect is only at 0 and p positions of benzene ring.

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