Statement 1 : The oxidation state of Cr in Al2(Cr2O7)3 is +3. Statement 2 : As a neutral compound, the sum of oxidation numbers of all the atoms must equal to zero.
A
Both Statement 1 and
Statement 2 are correct and Statement 2 is the correct explanation of
Statement 1.
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B
Both Statement 1 and
Statement 2 are correct and Statement 2 is not the correct explanation of
Statement 1.
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C
Statement 1 is
correct but Statement 2 is not correct.
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D
Statement 1 is
not correct but Statement 2 is correct.
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E
Both the Statement 1
and Statement 2 are not correct.
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Solution
The correct option is D
Statement 1 is
not correct but Statement 2 is correct.
Let X be the oxidation state of Cr in Al2(Cr2O7)3. The oxidation states of Al and O are +3 and -2 respectively. As a neutral compound, the sum of oxidation numbers of all the atoms must be equal to zero. Hence, 2(−3)+3[2X+7(−2)]=0 +6+3[2X−14]=0 +6+6X−42=0 6X=36 X=+6