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Question

Statement-1: The value of van der Waal's constant (a) is larger for ammonia than for nitrogen.
Statement-2: Hydrogen bonding is present in ammonia.

A
Statement-1 is True, Statement-2 is True; Statement-2 is a correct expalnation for Statment-1.
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B
Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for Statement-1
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C
Statement-1 is True, Statement-2 is False
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D
Statement-1 is False, Statement-2 is True
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Solution

The correct option is A Statement-1 is True, Statement-2 is True; Statement-2 is a correct expalnation for Statment-1.
The value of van der Waal's constant (a) is directly proportional to the force of attraction between the molecules. NH3 has hydrogen bonding whereas nitrogen has London dispersion force. As hydrogen bonding is stronger than London dispersion forces, ammonia has a larger force of attraction than nitrogen.
Thus, Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-1.

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