The correct option is A Statement-1 is True, Statement-2 is True; Statement-2 is a correct expalnation for Statment-1.
The value of van der Waal's constant (a) is directly proportional to the force of attraction between the molecules. NH3 has hydrogen bonding whereas nitrogen has London dispersion force. As hydrogen bonding is stronger than London dispersion forces, ammonia has a larger force of attraction than nitrogen.
Thus, Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-1.