Limiting radius ratio r/R | Coordinate Number of cation | Structural Arrangement ( Geometry of voids) | Example |
0.155−0.225 | 3 | Plance Trigonal | Boron Oxide |
0.225−0.414 | 4 | Tetrahedral | ZnS,SiO2 |
0.414−0.732 | 4 | Square planar | - |
0.414−0.732 | 6 | Octahedral | NaCl,MgO2 |
0.732−1.000 | 8 | Cubic | CsCl |