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Question

Statement I : If ΔH is positive and ΔS is positive, ΔG must be positive.
Statement II : ΔG=ΔHTΔS.

A
Statement 1 and Statement 2 are correct and Statement 2 is the correct explanation of Statement 1 .
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B
Both the Statement 1 and Statement 2 are correct and Statement 2 is not the correct explanation of Statement 1.
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C
Statement 1 is correct but Statement 2 is not correct.
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D
Statement 1 is not correct but Statement 2 is correct.
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E
Both the Statement 1 and Statement 2 are not correct.
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Solution

The correct option is D Statement 1 is not correct but Statement 2 is correct.
Statement 1: If ΔH is positive and ΔS is positive then ΔG is positive provided ΔH>TΔS.
Hence, statement 1 is false.
Statement 2: ΔG=ΔHTΔS
Hence, Statement 2 is true.
Therefore, statement 1 is wrong and statement 2 is correct.

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