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Question

Statement I : SO3 diffuses more slowly than CO2.
Statement II : SO3 has smaller bond angles.

A
Statement I is true, statement II is true and statement II is correct explanation of statement I
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B
Statement I is true, statement II is true and statement II is not correct explanation of statement I
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C
Statement I is true, statement II is false
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D
Statement I is false, statement II is true
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E
Statement I is false, statement II is false
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Solution

The correct option is C Statement I is true, statement II is true and statement II is not correct explanation of statement I
Statement I : SO3 diffuses more slowly than CO2.
The rate of diffusion is inversely proportional to the square root of molecular weight. SO3 having higher molecular weight diffuses more slowly than CO2 having lower molecular weight.

Statement II : SO3 has smaller bond angles than CO2.
CO2 has linear structure with OCO bond angle of 180 o. SO3 has trigonal planar structure with OSO bond angle of 120 o.
Hence, statement I is true, statement II is true and statement II is not the correct explanation of statement I.

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