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Question

Statement I : The oxidation state of Cr in Al2(Cr2O7)3 is +3.
Statement II : as a neutral compound, the sum of oxidation numbers of all the atoms must equal zero.

A
Statement 1 and Statement 2 are correct and Statement 2 is the correct explanation of Statement 1
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B
Both the Statement 1 and Statement 2 are correct and Statement 2 is NOT the correct explanation of Statement 1
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C
Statement 1 is correct but Statement 2 is not correct
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D
Statement 1 is not correct but Statement 2 is correct
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E
Both the Statement 1 and Statement 2 are not correct.
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Solution

The correct option is D Statement 1 is not correct but Statement 2 is correct
Oxidation state of Al is +3. And oxidation number of O is 2. Thus, oxidation state of Cr can be calculated by considering it as X. Thus-
(23) + 6X + [21(2)] = 0
The value of X obtained is +6. Oxidation state of Cr in the above mentioned molecule is +6.
In a neutral compound, the sum of oxidation numbers of all the atoms must be equal to zero. If it's not zero, it can't be neutral.
Thus, statement 1 is not correct. Statement 2 is correct.
Option D is the correct answer.

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