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Question


Statement: In case of meta-attack on aniline (where NH2 group is o-, p-directing) and in case of ortho-attack on nitrobenzene, resonating structures are possible. Meta-attack is more stable.

State whether the given statement is true or false.

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A
True
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B
False
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Solution

The correct option is A True
In case of nitrobenzene +ve charge developed at meta position is highly unstable the canonical structure but delocalisation of +ve charge in anilin, positive charge developed at the ortho and para positive which is stable canonical structure so, meta attack on aniline is more stable. It is true.
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