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Question

Steam undergoes decomposition at high temperature as per the reaction
H2O(g)H2(g)+12O2(g),ΔH=200kJmol1ΔS=40Jmol1
The temperature at which equilibrium constant is unit is :

A
3000 Kelvin
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B
5000 Kelvin
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C
5333 Kelvin
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D
5 Kelvin
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Solution

The correct option is B 5000 Kelvin
ΔG=ΔHTΔS=RTlnKeq=0[Keq=1].
T=ΔHΔS=200×10340=5000K

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