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Question

at 298 K and 1 atm pressure , solubility of N2 in water was found to be 6.8*10-4 mol/L . if the partial pressure of N2 is 0.78 atm . then what is the concentration of N2 dissolved in water under atmospheric conditions

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Solution

Henry's Law : p=KHCp=partial pressureKH=Henry's ConstantC = ConcentrationSo, Solubility of N2 at 1atm = 6.8×10-4mol/Lp=1 atmSo, KH=pC=16.8×10-4=1.47×103 atm/molWhen the partial pressure = 0.78 atmC = pKH=0.781.47×103=0.53×10-3=5.3×10-4 mol/L

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