For the reaction NH4Cl (s) NH3 (g) + HCL (g) at 25 , enthalpy change DH = +177 kJ per mole and entropy change triangle DS = +285 JK-1mol-1.Calculate free energy change DG at 25°C and predict whether the reaction is spontaneous or not.
Open in App
Solution
Dear student
NH4Cl = NH3 + HCl
dG = dH - TdS
For spontaneous reaction dG should be negative.
dG = 177 X 103 J/mol - 298K X 285 J/K-mol
dG = 92070 J/mol
OR 92.07 kj/mol