The correct option is B Conc. H2SO4,HCl
Reacting sodium chloride (salt) and sulfuric acid at elevated temperatures to produce sodium bisulfate and hydrogen chloride gas.
NaCl(s)+H2SO4(l)→HCl(g)+NaHSO4(s)
(Sodium bisulfate, also sodium hydrogen sulfate)
The reaction can also yield Na2SO4 but Sodium sulfate reacts with an equivalent amount of sulfuric acid to give an equilibrium concentration of the acid salt sodium bisulfate.