Sucrose decomposes in acid solution into glucose and fructose according to first order rate law with t1/2=3 Hrs. What fraction of the sample of sucrose remains after 8 hours?
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Solution
First order rate law is:
ln(A0At)=ktatt=t1/2=3h,At=0.5A0
On substitution: ln(A00.5A0)=k3k=0.231
At t=8h,At=concentration at time t
Substitution gives: ln(A0At)=0.231×8(AtA0)=0.1575
Therefore 15.75% of sucrose remains undecomposed after 8 hours.